(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (R,R)-Ph-BPE-Rh

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Supplier Alfa Chemistry
Product # ACM528565846
CAS # 528565-84-6
Pricing Inquire
Synonyms 528565-84-6;1,2-Bis[(2R,5R)-2,5-diphenylphospholano]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;(R,R)-Ph-BPE-Rh;(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;MFCD07369037;DTXSID20746256;PUBCHEM_71310600;(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(i)tetrafluoroborate;
IUPAC Name (1Z,5Z)-cycloocta-1,5-diene;(2R,5R)-1-[2-[(2R,5R)-2,5-diphenylphospholan-1-yl]ethyl]-2,5-diphenylphospholane;rhodium;tetrafluoroborate;
MolecularFormula C42H48BF4P2Rh-;
MolecularWeight 804.503g/mol
Application
  • 1. Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric hydrogenation.
  • 2. This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides.
  • 3. Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents.
  • 4. Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins.
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