(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride, 98% (S,S)-Jacobsen Cat.

• Supplier: Alfa Chemistry
• Product #: ACM135620041
• CAS #: 135620-04-1
• Synonyms: 135620-04-1;(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride;(S,S)-(N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine)manganese(III) chloride;C36H52ClMnN2O2;MFCD02101663;(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III)chloride;(S,S)-Jacobsen's catalyst(S, S) -(+)- N,N' -Bis (3,5 Di- tert -Butylsalicylidene)- 1,2 -Cyclohexanediaminomanganese (III) chloride
• IUPAC Name: 2,4-ditert-butyl-6-[[(1S,2S)-2-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]cyclohexyl]iminomethyl]phenol;manganese(3+);trichloride
• EC Number: 603-926-9
• MolecularFormula: C36H54Cl3MnN2O2
• MolecularWeight: 708.128g/mol
• Application:
  • Catalyst for the conversion of olefins to chiral epoxides in high enantiomeric excess.
  • Pharmaceutically important, single enantiomer amino alcohols are efficiently produced from the corresponding chiral epoxide by acid or base-catalyzed epoxide ring-opening reactions.
  • Asymmetric Kinetic resolution of secondary alcohols in water.
  • Enantioselective Reformatsky reaction with ketones.