[RuCl(p-cymene)((S)-tolbinap)]Cl

Supplier Alfa Chemistry
Product # ACM228120954
CAS # 228120-95-4
Pricing Inquire
Synonyms SC10123; (R)-RuCl[(p-cymene)(T-BINAP)]Cl; Chloro[(R)-(+)-2,2 -bis(di-p-tolylphosphino)-1; CHLORO[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM(II) CHLORIDE; MFCD09753014; (S)-RuCl[(p-cymene)(T-BINAP)]Cl; C58H54Cl2P2Ru;
IUPAC Name [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane;dichlororuthenium;1-methyl-4-propan-2-ylbenzene;
MolecularFormula C58H54Cl2P2Ru;
MolecularWeight 984.988g/mol
Application
  • 1. Useful ligand for palladium-catalyzed carbon-oxygen bond formation.
  • 2. Ligand for palladium-catalyzed α-arylation of ketones.
  • 3. Ligand for Cu-catalyzed asymmetric conjugate reduction.
  • 4. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes.
  • 5. Enantioselective conjugate reduction of lactones and lactams.
  • 6. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters.
  • 7. Catalytic Aldol reaction to ketones.
  • 8. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes.
  • 9. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes.
  • 10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols.
  • 11. Rhodium-catalyzed cross cyclotrimerization.
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