(S)-1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)piperidine

Supplier Alfa Chemistry
Product # ACM284472793
CAS # 284472-79-3
Pricing Inquire
Synonyms 879083-09-7; AJ-108734; SC11376; (S)-(+)-4-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl-piperidine; (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a; SCHEMBL15422481; (R)-1-(DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-YL)PIPERIDINE; 2,2'-[(Piperidinophosphinediyl)dioxy]-1,1'-binaphthalene; 636559-55-2; ZINC43681909;
IUPAC Name 1-(12,14-dioxa-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-yl)piperidine;
MolecularFormula C25H22NO2P;
MolecularWeight 399.43g/mol
Application
  • Ligand used in the enantioselective rhodium catalyzed low pressure high activity hydrogenation of α-dehydroaminoesters, enamides, and dimethylitaconate.
  • Ligand used in asymmetric hydrogenation of 2-substituted N-protected indoles using Rhodium-based catalysts.
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