(4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride acetonitrile adduct

Supplier Alfa Chemistry
Product # ACM328123042
CAS # 328123-04-2
Pricing Inquire
Synonyms 328123-04-2;(4R,5R)-(-)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOLATO[1,2-BIS(DIMETHOXY)ETHANE]TITANIUM (IV) DICHLORIDE;MFCD04973054;SC10833;Tetraphenyl-TADDOL-DME-titaniumdichloride;123D042;(4R,5R)-(-)-2,2-Di-Me-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(diMeO)ethane]Ti(IV) dichloride CH3CN adduct;(4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato(1,2-bis(dimethoxy)ethane)titanium(IV) dichloride;(4R,5R)-(-)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOLATO[1,2-BIS(DIMETHOXY)ETHANE]TITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT;
IUPAC Name acetonitrile;cyclohexa-1,3-dien-1-yl-[(4R,5R)-5-[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl]-phenylmethanol;dichlorotitanium;1,2-dimethoxyethane;
MolecularFormula C37H45Cl2NO6Ti;
MolecularWeight 718.535g/mol
Application
  • Catalyst used in the enantioselective fluorination of β-ketoesters.
  • Versatile catalyst used in the enantioselective 1,2 and 1,4 additions to carbonyl compounds, transfer of allyl groups to aldehydes, cycloadditions and others.
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