(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (S,S)-Ph-BPE-Rh

• Supplier: Alfa Chemistry
• Product #: ACM849950534
• CAS #: 849950-53-4
• Synonyms: 849950-53-4;(S,S)-Ph-BPE-Rh;DTXSID60746255;PUBCHEM_71310599;MFCD07369038;(+)-1,2-Bis(2S,5S)-2,5-diphenylphospholano)ethane-(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate;1,2-Bis[(2S,5S)-2,5-diphenylphospholano]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;1,2-Bis[(s,s)-2,5-diphenylphospholano]ethane-(1,5-cycloocta-diene)rhodium(I)tetrafluoroborate
• IUPAC Name: (1Z,5Z)-cycloocta-1,5-diene;(2S,5S)-1-[2-[(2S,5S)-2,5-diphenylphospholan-1-yl]ethyl]-2,5-diphenylphospholane;rhodium;tetrafluoroborate
• MolecularFormula: C42H48BF4P2Rh-
• MolecularWeight: 804.503g/mol
• Application:
  • Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric hydrogenation.
  • This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides.
  • Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents.
  • Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins.