(Sa,R,R)-SIPHOS-PE

• Supplier: Alfa Chemistry
• Product #: ACM500997706-1
• CAS #: 500997-70-6
• Synonyms: 500997-69-3; (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1 inverted exclamation marka, 7 inverted exclamation marka-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine; (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE; (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1 inverted exclamation marka, 7 inverted exclamation marka-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine; 997S693; SCHEMBL19695663; RT-015574; CTK8E6816; (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1, 7-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine,N-Di[(R)-1-phenylethyl]-[(R)-1,1-spirobiindane-7,7-diyl]-phosphoramidite; (S)-SIPHOS-PE
• IUPAC Name: N,N-bis[(1R)-1-phenylethyl]-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine
• MolecularFormula: C33H32NO2P
• MolecularWeight: 505.598g/mol
• Application:
  • Chiral ligands for copper-catalyzed asymmetric allylic alkylation with dialkylzincs.
  • Chiral ligands for copper-catalyzed asymmetric conjugate addition of diethylzinc to enones.
  • Chiral ligands for palladium-catalyzed asymmetric hydrosilylation of styrenes
  • Chiral ligands for copper-catalyzed asymmetric ring-opening of oxabicyclic alkenes with Grignard reagents.
  • Chiral ligands for nickel-catalyzed asymmetric hydrovinylation of α-alkyl vinylarenes.
  • Chiral ligands for iridium-catalyzed asymmetric hydrogenation of cyclic enamines.
  • Chiral ligands for iridium-catalyzed asymmetric hydrogenation of cyclic imines.
  • Chiral ligands for gold-catalyzed asymmetric [2 + 2] cycloaddition reaction.
  • Chiral ligands for rhodium-catalyzed asymmetric hydroacylation of salicylaldehydes to homoallylic sulfides.
  • Chiral ligands for palladium-catalyzed asymmetric carboamination reactions.