2-Dicyclohexylphosphino-2',6'-diisopropoxybiphenyl

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Supplier Alfa Chemistry
Product # ACM787618228
CAS # 787618-22-8
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Synonyms AX8074362; MFCD06798294 (95%); X3474RY19E; CTK8B4848; ANW-46517; 2-DICYCLOHEXYLPHOSPHINO-2',6'-DI-I-PROPOXY-1,1'-BIPHENYL; RW2258; dicyclohexyl-[2-(2,6-diisopropoxyphenyl)phenyl]phosphane; AC-28790; Dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine;
IUPAC Name dicyclohexyl-[2-[2,6-di(propan-2-yloxy)phenyl]phenyl]phosphane;
EC Number 616-653-5
MolecularFormula C30H43O2P;
MolecularWeight 466.646g/mol
Application
  • Versatile Ligand for the Pd-catalyzed coupling of secondary arylamines and alkylamines.
  • Ligand used for the Pd-catalyzed Negishi cross-coupling reaction of (hetero)arylchlorides.
  • Synthesis of ladder-type π-conjugated heteroacenes via palladium-catalyzed double N-arylation and intramolecular O-arylation.
  • A palladium-catalyzed regiospecific synthesis of N-aryl benzimidazoles,
  • Versatile ligand used for the Pd-catalyzed C-N coupling reaction of secondary aryl- and alkyl-amines at low temperature with the Pd precatalyst.
  • Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling of aryl chloride and NHC-boranes.
  • Ligand for the palladium-catalyzed trifluoromethylation of hindered aryl chlorides.
  • Ligand used for the palladium-catalyzed coupling of alkyl boronates.
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