Phenyl-[(R)-1,1'-spirobiindane-7,7'-diyl]-phosphite((R)-ShiP)

• Supplier: Alfa Chemistry
• Product #: ACM656233533
• CAS #: 656233-53-3
• Synonyms: AB1005807; (R)-ShiP; AKOS015950895; Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin,10,11,12,13-tetrahydro-5-phenoxy-,(11ar)-; (aR)-7,7'-(Phenoxyphosphinidenebisoxy)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]; (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy; (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1|I,7|I-fg][1,3,2]dioxaphosphocin-5-phenoxy; 885701-71-3; Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite; 7,7'-(Phenoxyphosphinidenebisoxy)-1,1'-spirobiindan
• IUPAC Name: 12-phenoxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine
• MolecularFormula: C23H19O3P
• MolecularWeight: 374.376g/mol
• Application:
  • Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids.
  • Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids.
  • Chiral ligands for rhodium-catalyzed arylation of α-ketoesters with arylboronic acids.
  • Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.
  • Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-β-arylenamides.