2-(Dicyclohexylphosphino)-2'-(dimethylamino)biphenyl

• Supplier: Alfa Chemistry
• Product #: ACM213697531
• CAS #: 213697-53-1
• Synonyms: 2-di-cyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl; 118492-EP2272832A1; (2'-dicyclohexylphosphanyl-biphenyl-2-yl)dimethyl-amine; 2-(Dicyclohexylphosphino)-2'-(N,N-diMethylaMino)biphenyl, 98% DavePhos; (2'-dicyclohexylphosphanyl -biphenyl-2-yl)-dimethyl-amine; Buchwald phosphine ligands, davephos phosphine ligand-; 2-dicyclohexylphosphino-2'-(N,N'-dimethylamino)biphenyl; [1,1'-BIPHENYL]-2-AMINE, 2'-(DICYCLOHEXYLPHOSPHINO)-N,N-DIMETHYL-; 2'-(dicyclohexylphosphino)-N,N-dimethyl-2-biphenylamine; RL02630
• IUPAC Name: 2-(2-dicyclohexylphosphanylphenyl)-N,N-dimethylaniline
• MolecularFormula: C26H36NP
• MolecularWeight: 393.555g/mol
• Application:
  • Ligand used in the Pd-catalyzed Suzuki coupling and animation of unactivated aryl chlorides. The reactions generally occur at room temperature and give high yields of product.
  • Ligand used in Pd-catalyzed C-N bond formation. A general synthesis of N6-aryl-2'deoxyadenosine analogues.
  • Ligand used in Pd-catalyzed N-arylation of indoles.
  • Ligand used in Pd-catalyzed synthesis of aryl-tert-butyl ethers.
  • Effective ligand in the Pd-catalyzed arylation of ester enolates.
  • Ligand employed in arylation of ketone enolates using ortho-halo nitrobenezenes.
  • Ligand employed in the amination of aryl nonaflates using Pd catalysts.
  • Ligand used for cascade alkenyl amination/Heck reaction for the synthesis of indoles.
  • Ligand used in Pd-catalyzed Kumada-Corriu cross coupling at low temperatures.
  • Ligand used in Rh-catalyzed intramolecular hydroamination of unactivated terminal and internal alkenes with primary and secondary amines.
  • Ligand used in Au-catalyzed cycloisomerization of allenes.