N-Dimethyl-[(S)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite((S)-SIPHOS)

• Supplier: Alfa Chemistry
• Product #: ACM443965104
• CAS #: 443965-10-4
• Synonyms: N-Dimethyl-[(R)-1,1 inverted exclamation marka-spirobiindane-7,7 inverted exclamation marka-diyl]phosphoramidite; MFCD08459340; (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1 inverted exclamation marka,7 inverted exclamation marka-fg][1,3,2]dioxaphosphocin-5-dimethylamine; (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1\',7\'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE; AB1005806; CS-0062402; AKOS015950893; SCHEMBL13324483; (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine; (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1,7-fg][1,3,2]dioxaphosphocin-5-dimethylamine,N-Dimethyl-[(R)-1,1-spirobiindane-7,7-diyl]phosphoramidite
• IUPAC Name: N,N-dimethyl-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine
• MolecularFormula: C19H20NO2P
• MolecularWeight: 325.348g/mol
• Application:
  • Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of α-dehydroamino esters.
  • Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of itaconic acid derivatives.
  • Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of β-dehydroaminoesters.
  • Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of enamides.
  • Chiral ligands for rhodium-catalyzed asymmetric Pauson-Khand reaction.
  • Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.