(R)-SITCP

• Supplier: Alfa Chemistry
• Product #: ACM856407379
• CAS #: 856407-37-9
• Synonyms: (R)-SITCP; CS-212; (S)-(-)-SITCP; 5-Phenyl-5,6,10,11,12,13-hexahydro-4H-diindeno[7,1-cd:1\',7\'-ef]ph osphocine; AB1005819; (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd; CS-0037626; CS-0037625; (S)-dimethylene-[7,7 inverted exclamation marka-(1,1 inverted exclamation marka-spiroindan)]-phenylphospholane; 7,7'-(Phenylphosphinediylbismethylene)-1,1'-spirobiindan
• IUPAC Name: 10-phenyl-10-phosphapentacyclo[10.6.1.11,4.016,19.08,20]icosa-4(20),5,7,12,14,16(19)-hexaene
• MolecularFormula: C25H23P
• MolecularWeight: 354.433g/mol
• Application:
  • Phosphine-catalyzed intra-and intermolecular gamma-addition of nitrogen nucleophiles to allenoates and alkynoates.
  • Catalytic asymmetric construction of the tryptanthrin skeleton via enantioselective decarboxylative [4+2] cyclization.
  • Catalytic, enantioselective carbon-oxygen bond formation - phosphine-catalyzed synthesis of benzylic esters via oxidation of benzylic C-H bonds.
  • Use of a new spirophosphine to achieve catalytic, enantioselective [4+1] annulations of amines with allenes to generate dihydropyrroles.