2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl

Ligand used in a Pd-catalyzed Suzuki coupling leading to C-15 analogs of vindoline.Direct annulation of 2-haloanilines to indoles and tryptophans catalyzed by Pd. Synthesis of regioregular polythiophenes. Preferred ligand for greener Sonogashira coupling in TPGS-750-M. Preferred ligand for greener Sonogashira coupling in TPGS-750-M.On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors XPhos may be used as a ligand in the following reactions: Preparation of functionalized benzylic sulfones via palladium-catalyzed Negishi cross-coupling between alkyl sulfones and aryl halides; Along with pre-milled palladium(II) acetate as a pre-catalyst for the Stille cross-coupling of aryl chlorides with tributylarylstannanes to form the corresponding biaryl compounds; Along with platinum chloride to catalyze the hydrosilylation of terminal arylalkynes with silanes to form functionalized β-(E)-vinylsilanes. Ligand for increased scope of Pd-catalyzed amination and amidation via arene sulfonates, aryl halides.

• Supplier: BOC Sciences
• Product #: BB029364
• Cas: 564483-18-7
• Molecular Weight: 476.72
• Molecular Formula: C33H49P
• Canonical SMILES: CC(C)C1=CC(=C(C(=C1)C(C)C)C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4)C(C)C