(R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (R,R)-QuinoxP*

Supplier Alfa Chemistry
Product # ACM866081621
CAS # 866081-62-1
Pricing Inquire
Synonyms AK173366; 866081-62-1; (R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline; (R,R)-QuinoxP; (R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline;
IUPAC Name (R)-tert-butyl-[3-[tert-butyl(methyl)phosphanyl]quinoxalin-2-yl]-methylphosphane;
MolecularFormula C18H28N2P2;
MolecularWeight 334.384g/mol
Application
  • Ligand for the rhodium-catalyzed, asymmetric hydrogenation of dehydroamino acid esters and α-enamides.
  • Ligand for the rhodium-catalyzed, asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds.
  • Ligand for the rhodium-catalyzed, asymmetric alkylative ring opening reaction
  • Ligand for the palladium-catalyzed asymmetric allylic alkylation and amination of racemic substrates.
  • Ligand for the ruthenium-catalyzed asymmetric hydrogenation of ketones.
  • Ligand for the rhodium-catalyzed, asymmetric hydroacylation of 1,1-disubstituted alkenes with aldehydes.
  • Ligand for the silver-catalyzed asymmetric nitroso aldol reaction.
  • Cu-catalyzed enantioconvergent allyllic borylation.
  • Cu-catalyzed enantioselective cyclopropylation.
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